The Mac @TheMac
26 November, 03:36
Magnetochemistry is concerned with the magnetic properties of chemical compounds. Magnetic properties arise from the spin and orbital angular momentum of the electrons contained in a compound. Compounds are diamagnetic when they contain no unpaired electrons. Molecular compounds that contain one or more unpaired electrons are paramagnetic. The magnitude of the paramagnetism is expressed as an effective magnetic moment, μeff. For first-row transition metals the magnitude of μeff is, to a first approximation, a simple function of the number of unpaired electrons, the spin-only formula. In general, spin-orbit coupling causes μeff to deviate from the spin-only formula. For the heavier transition metals, lanthanides and actinides, spin-orbit coupling cannot be ignored. Exchange interaction can occur in clusters and infinite lattices, resulting in ferromagnetism, antiferromagnetism or ferrimagnetism depending on the relative orientations of the individual spins.

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The Mac @TheMac
26 November, 03:41
In response The Mac to his Publication

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The Mac @TheMac
26 November, 03:43
In response The Mac to his Publication
Magnetoelectrochemistry is a branch of electrochemistry dealing with magnetic effects in electrochemistry.

These effects have been supposed to exist since the time of Michael Faraday. There have also been observations on the existence of Hall effect in electrolytes. Until these observations, magnetoelectrochemistry was an esoteric curiosity, though this field has had a rapid development in the past years and is now an active area of research. Other scientific fields which contributed to the development of magnetoelectrochemistry are magnetohydrodynamics and convective diffusion theory.

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The Mac @TheMac
26 November, 03:46
In response The Mac to his Publication
esoteric
intended for or likely to be understood by only a small number of people with a specialized knowledge or interest.

"esoteric philosophical debates"

abstruse
obscure
arcane
recherché
rarefied
recondite
abstract
difficult
hard
puzzling
perplexing
enigmatic
inscrutable
cryptic
Delphic
complex
complicated
involved
over/above one's head
incomprehensible
opaque
unfathomable
impenetrable
mysterious
occult
little known
hidden
secret
private
mystic
magical
cabbalistic
involuted

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The Mac @TheMac
26 November, 03:48
In response The Mac to his Publication
mid 17th century: from Greek esōterikos, from esōterō, comparative of esō ‘within’, from es, eis ‘into’. Compare with exoteric.

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The Mac @TheMac
26 November, 03:52
In response The Mac to his Publication
exoteric
/ˌɛksə(ʊ)ˈtɛrɪk/

FORMAL
adjective: exoteric
intended for or likely to be understood by the general public.

Origin

mid 17th century: via Latin from Greek exōterikos, from exōterō ‘outer’, comparative of exō ‘outside’.

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The Mac @TheMac
26 November, 03:54
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The Mac @TheMac
26 November, 03:55
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The Mac @TheMac
26 November, 03:57
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The Mac @TheMac
26 November, 04:15
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The Mac @TheMac
26 November, 04:15
In response The Mac to his Publication

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The Mac @TheMac
26 November, 04:16
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The Mac @TheMac
26 November, 04:17
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The Mac @TheMac
26 November, 04:20
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The Mac @TheMac
26 November, 04:21
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The Mac @TheMac
26 November, 04:22
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The Mac @TheMac
26 November, 04:27
In response The Mac to his Publication

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The Mac @TheMac
26 November, 04:27
In response The Mac to his Publication

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The Mac @TheMac
This study investigates the response of magnetic nanoparticles (MNPs), dispersed in a viscoelastic hydrogel, to an external rotating magnetic field (RMF) for the purpose of developing a new class of magneto-responsive materials with tunable mass transport properties. Ferrogels were prepared by chemical cross-linking and polymerization of acrylamide in colloidal dispersions of thermally blocked MNPs of cobalt ferrite. Magnetization measurements of ferrogels in a swollen state revealed a transitional state from ferromagnetism to superparamagnetism through the shrinkage of hysteresis loops and the reduction of remanent magnetization. A quantitative analysis of magnetization data indicated the existence of hydrodynamically free MNPs, susceptible to Brownian relaxation along with the blocked ones. It was found through rheological analysis that inclusion of MNPs within the polymer matrix significantly alters the ferrogel's elasticity. At low chemical crosslinking ratios, MNPs improve elastic
04:28 PM - Nov 26, 2021
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The Mac @TheMac
26 November, 04:30
In response The Mac to his Publication
through the formation of physical crosslinks ensued by reduction in the fraction of the free MNPs. As the crosslinking ratio was increased, the polymer network showed a tendency toward blockage of more MNPs. Effective diffusion coefficients in both particle-free hydrogels and ferrogels were obtained by measuring the release kinetics of a model compound in the absence and presence of an external low-frequency RMF. Experimental results showed that conversion of magnetic energy to kinetic energy by rotational movement of the free MNPs in a RMF escalates mass transport provided that hydrodynamically free MNPs are available within the ferrogels. The effectiveness of excitation by a RMF showed correlation with the density of free MNPs. Release experiments at constant RMF intensity and various frequencies revealed augmentation of effective diffusivities as the frequency was increased from 10 to 75 Hz.

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The Mac @TheMac
26 November, 04:33
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